Carboxymethyl Cellulose-Ammonium Chloride on Electrical of Plasticized Propylene Carbonate Solid Bio-Polymer Electrolytes (SBPs) using Experimental and Computational Studies

The thermal conductivity have been carried out based on carboxyl methylcellulose (CMC) doped with ammonium chloride (AC) with varied amount (0 - 12 wt. %) of propylene carbonate (PC) solid bio-polymer electrolytes (SBPs) via... [ view full abstract ]

The thermal conductivity have been carried out based on carboxyl methylcellulose (CMC) doped with ammonium chloride (AC) with varied amount (0 - 12 wt. %) of propylene carbonate (PC) solid bio-polymer electrolytes (SBPs) via solution casting technique. In SBPs system, the frequency dependence of ionic conductivity, ε_r, and M_i have been measured by using electrical impedance spectroscopy method in the temperature range of 303 – 328 K. The highest ionic conductivity on the SBPs system is 1.01 x 10^-2 S cm^-1 for sample containing 8 wt. % of PC. The system was found to obey Arrhenius rule where R² ≈ 1. The dielectric studies show non-Debye behaviour for CMC-AC-PC SBPs. It is convenience to trust that the PC is one of the most promising plasticizer to enhance the ionic conductivity and performance for SBP system.