Boryl Radicals and Anions, Borylenes, Diboranes, Neutral and Dianionic Diborenes: Diverse Reduction Chemistry of cAAC-Supported Hydroboron Halides

Merle Arrowsmith

Institute for Sustainable Chemistry & Catalysis with Boron and Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg

Merle Arrowsmith obtained her B.Sc. Hons. degree in 2006 from Chimie ParisTech, France, and her Ph.D. in 2011 after completion of her research on Group 2 catalysis with Professor Michael S. Hill at the University of Bath, UK. After a postdoctoral stay in the same group (2011–2014) she has been working since 2014 as an Alexander von Humboldt Postdoctoral Fellow and now Research Associate in the group of Professor Holger Braunschweig at the University of Würzburg, Germany.

Abstract

First designed by Bertrand and co-workers in 2005 cyclic alkyl(amino)carbenes (cAACs)1 have since enabled the isolation of a wide range of hitherto inaccessible low-valent and radical main group species.2 In this... [ view full abstract ]

Authors

  1. Merle Arrowsmith (Institute for Sustainable Chemistry & Catalysis with Boron and Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg)
  2. Holger Braunschweig (Institute for Sustainable Chemistry & Catalysis with Boron and Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg)

Topic Areas

B - Advanced synthesis and characterization , B - General aspects of inorganic chemistry

Session

OS2a-217a » Advanced synthesis and characterization (13:30 - Tuesday, 4th July, 217a)

Presentation Files

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