Recent advances with association theories

While the foundations of thermodynamics are well-established (in most areas), the quest for better thermodynamic models continues, especially for advanced and complex applications.  While classical thermodynamic models are... [ view full abstract ]

While the foundations of thermodynamics are well-established (in most areas), the quest for better thermodynamic models continues, especially for advanced and complex applications.  While classical thermodynamic models are still useful in several practical applications, many of the new generation thermodynamic models are based on the concept of association. These models, known since the early 20^th century, have become well-known especially over the last 30-40 years and they have offered a unique possibility to use applied thermodynamics in areas and with an accuracy never experienced before. 

Selected recent advances in both theory and application of association models will be presented. The following areas will be highlighted: simultaneous description of critical point and equilibrium properties, quadrupolar mixtures, asphaltenes, electrolytes and aqueous systems.